Molecular coating enhances organic solar cells

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An electrode coating just one molecule thick can significantly enhance the performance of an organic photovoltaic cell, KAUST researchers have found. The coating outperforms the leading material currently used for this task and may pave the way for improvements in other devices that rely on organic molecules, such as light-emitting diodes and photodetectors.

Unlike the most common photovoltaic cells that use to harvest light, organic photovoltaic cells (OPVs) rely on a light-absorbing layer of carbon-based molecules. Although OPVs cannot yet rival the performance of silicon , they could be easier and cheaper to manufacture at a very large scale using printing techniques.

When light enters a photovoltaic cell, its energy frees a negative electron and leaves behind a positive gap, known as a hole. Different materials then gather the electrons and holes and guide them to different electrodes to generate an . In OPVs, a material called PEDOT:PSS is widely used to ease the transfer of generated holes into an electrode; however, PEDOT:PSS is expensive, acidic and can degrade the cell's performance over time.

The KAUST team has now developed a better alternative to PEDOT:PSS. They use a much thinner coating of a hole-transporting molecule called Br-2PACz, which binds to an (ITO) electrode to form a single-molecule layer. The organic cell using Br-2PACz achieved a of 18.4 percent, whereas an equivalent cell using PEDOT:PSS reached only 17.5 percent.

"We were very surprised indeed by the performance enhancement," says Yuanbao Lin, Ph.D. student and member of the team. "We believe Br-2PACz has the potential to replace PEDOT:PSS due to its low cost and high performance."

Br-2PACz increased the cell's efficiency in several ways. Compared with its rival, it caused less , improved hole transport and allowed more light to shine through to the absorbing layer. Br-2PACz also improved the structure of the light-absorbing layer itself, an effect that may be related to the coating process.

The coating could even improve the recyclability of the solar cell. The researchers found that the ITO electrode could be removed from the cell, stripped of its coating and then reused as if it was new. In contrast, PEDOT:PSS roughens the surface of the ITO so that it performs poorly if reused in another cell. "We anticipate this will have a dramatic impact on both the economics of OPVs and the environment," says Thomas Anthopoulos, who led the research.


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More information: Yuanbao Lin et al, 18.4 % Organic Solar Cells Using a High Ionization Energy Self‐Assembled Monolayer as Hole‐Extraction Interlayer, ChemSusChem (2021). DOI: 10.1002/cssc.202100707
Citation: Molecular coating enhances organic solar cells (2021, June 10) retrieved 21 June 2021 from https://techxplore.com/news/2021-06-molecular-coating-solar-cells.html
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