November 3, 2022

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Adding passive contacts to spur solar cell development

Schematic diagrams of sample structure used for contact resistivity measurements by the Cox–Strack method and the corresponding schematic energy-level diagrams for a) pure TiO x , b) Al y TiO x , c) TiO x /Al y TiO x stacks, and Al y TiO x /TiO x. Credit: Solar RRL (2022). DOI: 10.1002/solr.202200550
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Schematic diagrams of sample structure used for contact resistivity measurements by the Cox–Strack method and the corresponding schematic energy-level diagrams for a) pure TiO x , b) Al y TiO x , c) TiO x /Al y TiO x stacks, and Al y TiO x /TiO x. Credit: Solar RRL (2022). DOI: 10.1002/solr.202200550

An increase in the efficiency of solar panels may be on the horizon, as research from The Australian National University (ANU) reduces their current limitations.

ANU researchers have found a way to improve the performance of photovoltaic (PV) or solar cells. This is done through the addition of "passivating contacts" between the metal and silicon parts of the solar cell, making it more productive.

"These findings will help push the performance of silicon solar cells closer to their theoretical limit," Mohamed Ismael, lead ANU researcher and Ph.D. candidate said.

"Each day, the sun produces significantly more energy than needed to power the whole planet. The only limitation is our ability to economically convert it to electricity," he said.

Solar cells are devices that convert in the form of photons into . As it stands, solar cells aren't operating at their maximum capacity due to substantial electrical losses associated with the direct contact of metals with silicon.

"Transition metal oxides such as titanium oxide have many qualities that make them ideal as passivating contact layers," Dr. Lachlan Black said.

"This isn't a new idea, but the way in which we combined these layers has produced better results and higher operating voltages than anything previously reported."

The research team is hoping to develop the technology to a point where it can be applied to industrial solar cells on a large scale.

The PV market is a multi-billion-dollar industry, with silicon solar cells contributing to 95 percent of all commercial solar cells. They are predicted to remain dominant for the foreseeable future given their advantageous properties compared to competitors.

"If successful, we could see our technology in almost all new solar panels installed on your roof or utility-scale solar plants," Dr. Black said.

Some practical issues still need to be addressed before the technology can be implemented, but the PV community is already working to solve these challenges.

"Improving the efficiency of guarantees more at a reduced cost. This not only helps to address , but opens up new economic opportunities for this low-cost clean energy," Ismael said.

The research paper was published in Solar RRL.

More information: Mohamed M. Shehata et al, Outstanding Surface Passivation for Highly Efficient Silicon Solar Cells Enabled by Innovative Al y TiO x /TiO x Electron‐Selective Contact Stack, Solar RRL (2022). DOI: 10.1002/solr.202200550

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