Hydrogel technology boosts efficiency and stability of gas evolution reactions
A team of researchers from UNIST has achieved a remarkable breakthrough in the production of clean gas raw materials, particularly green hydrogen. By developing a hydrogel thin film technology, the team has paved the way for a revolution in gas-producing electrodes, significantly enhancing production efficiency and expediting the commercialization of green hydrogen production.
Under the leadership of Professor Jungki Ryu and Professor Dong Woog Lee in the School of Energy and Chemical Engineering at UNIST, the research team has successfully created a large-area hydrogel thin film technology that can be universally applied to gas-evolving electrodes. By leveraging the application of a hydrogel thin film, akin to those commonly found in cosmetics, the researchers have made remarkable strides in boosting the production efficiency of gaseous raw materials generated through electrochemical reactions.
This cutting-edge technology facilitates the seamless release of gas raw materials, mitigating the accumulation on the electrode surface, which has long been a significant challenge in gas evolution reactions. The paper is published in the journal Advanced Functional Materials.
During electrochemical reactions, such as water electrolysis, gases like hydrogen, oxygen, and nitrogen are produced. However, these gases often become trapped as air bubbles on the electrode surface, impeding electrolyte permeation and diminishing overall efficiency.
To overcome this critical issue, the research team ingeniously coated the electrode surface with a hydrogel layer featuring porous structures, thereby enabling efficient gas exchange and the swift removal of gas bubbles. The hydrogel employed in this study is a readily available material with high hydrophilicity, commonly utilized in cosmetics, ointments, and diapers.
The application of the hydrogel-coated electrode system has yielded remarkable results. By expeditiously eliminating gas bubbles through the hydrophilic hydrogel coating, electrolytes could permeate the electrode promptly, thereby enhancing efficiency. The system achieved an impressive increase in gas production efficiency of up to 2.3 times when implemented with nickel and platinum catalysts, marking a significant advancement from 65.7 mA/cm² to 151.5 mA/cm².
Moreover, the prevention of gas accumulation on the electrode surface mitigates strain on the catalyst, reducing the risk of clumping or peeling and ensuring the long-term stability of the electrolytic system. This technology possesses the potential to revolutionize electrochemical gas generation reactions, particularly in water electrolysis, thus making a substantial contribution to the commercialization of green hydrogen.
"This hydrogel-based technology represents a creative approach to significantly enhance the efficiency of electrochemical gas generation reactions," noted Professor Ryu. "By applying hydrogel, a commonly used material in everyday products such as wet bands, cosmetics, and diapers, to electrodes, we can drive advancements in water electrolysis reactions and expedite the commercialization of green hydrogen."
More information: Yunseok Kang et al, Versatile, Stable, and Scalable Gel‐Like Aerophobic Surface System (GLASS) for Hydrogen Production, Advanced Functional Materials (2023). DOI: 10.1002/adfm.202308827