Controlling dendrites reveals secret to rechargeable lithium electrode

Controlling dendrites reveals secret to rechargeable lithium electrode
From left, IUPUI's Jian Xie, Yadong Liu and Fan Yang have helped unlock the secret to a revolutionary battery. Credit: School of Engineering and Technology at IUPUI

Imagine your cellphone being as thin as a piece of paper and not in need of near-constant charging.

That's possible with the manipulation of a 's dendrites, says Jian Xie, an Indiana University-Purdue University Indianapolis professor of mechanical engineering and a research member of the IUPUI Integrated Nanosystems Development Institute.

In a paper recently published in Nature Energy, Xie and a team of authors—including School of Engineering and Technology postdoctoral research associates Yadong Liu and Le Xin, postgraduate student Qi Liu, and Ph.D. student Fan Yang—detail how they have solved a decades-old problem with lithium electrodes in batteries.

For battery manufacturers, how to make a rechargeable metal has proved frustratingly elusive. Such an electrode would make batteries 10 times more powerful than those currently used in a number of applications.

The fault lies in the dendrites.

Dendrites are crystals that grow inside , in a style similar to trees. As they grow in every direction, they eventually span the entire electrode and short-circuit the battery, making it no longer rechargeable.

Engineers have tried to prevent dendrites from forming at all, but that goes against the metal's nature. Instead, Xie and his team allow the dendrites to form but change their growth direction so they grow in a densely packed layer that doesn't adversely affect the battery. The end result is revolutionary, allowing for safe recharging and high capacity.

"We designed the working principle based on electroplating, and the experiment turned out to work exactly as designed—a rarity in my 35-year research career," Xie said. "The possibilities for this application are numerous, and we feel the work can be further improved in the years to come."

Lithium metal electrodes have the highest theoretical specific capacity of energy density, at 3,863 mAh/g (milliAmpere-hour/grams). By comparison, an everyday graphite/hard carbon electrode is only 330 mAh/g.

The expected applications for such a breakthrough battery could include microelectronics, medical devices, electric vehicles, drones, military uses and, yes, portable electronics such as cellphones.


Explore further

Study suggests route to improving rechargeable lithium batteries

More information: Yadong Liu et al. Making Li-metal electrodes rechargeable by controlling the dendrite growth direction, Nature Energy (2017). DOI: 10.1038/nenergy.2017.83
Journal information: Nature Energy

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Jul 21, 2017
"We designed the working principle based on electroplating, and the experiment turned out to work exactly as designed—a rarity in my 35-year research career,"

Love that statement. Yes, research always involves getting it wrong a lot of the time before you finally get it right. That's something that isn't obvious to the public (because the failures don't get published)

Takeaway message 1:
1) Scientists aren't infallible
2) Science is hard work and not just one brilliant idea after another (90% prespiration and 10% inspiration)
3) When they DO publish it's based off of a LOT of work and making doubly damn sure that what they publish is correct.

Takeaway message 2:
When you hear people on here expounding ideas that they never tested (or even wrote down)...forget about it. It's crankery.

Jul 21, 2017
Makes you wonder how greatly it would affect the world.

Jul 21, 2017
Well here's hoping that it works as planned. Star Trek never fails to come true , of sorts. We are placing huge hopes on lithium while they powered their ship with fictional dilithium crystals way before lithium was used for energy storage.

boc
Jul 22, 2017
Energy density in Ah/g? There is a big difference between an A (ampere) and W (watt).
How could you measure energy density of a only one electrode?

Jul 22, 2017
"Energy density in Ah/g?"


For the same chemical composition, the charge density is directly translateable to energy density because the voltage stays constant.

Jul 24, 2017
I wonder if the 'dentrite bush' would act to increase the surface area of the electrode - these batteries would get better over time?

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