Charging ahead to higher energy batteries

Charging ahead to higher energy batteries
Image (a) is a cross-sectional SEM image of the Li5La3Nb2O12 crystal layer and image (b) shows computationally simulated trajectories of the Li, La, Nb, and O framework atoms obtained for Σ3 (2-1-1) = (1-21) at a temperature of 1300 K. Credit: Nobuyuki Zettsu Ph.D., the Center for Energy and Environmental Science, the Department of Materials Chemistry, Shinshu University.

Researchers have developed a new way to improve lithium ion battery efficiency. Through the growth of a cubic crystal layer, the scientists have created a thin, dense connecting layer between the electrodes of the battery. Professor Nobuyuki Zettsu and Professor Katsuya Teshima led the research. The authors published their results in Scientific Reports.

"Owing to some intrinsic characteristics of liquid electrolytes, such as low lithium transport number, complex reaction at the solid/liquid interface, and thermal instability, it has not been possible to simultaneously achieve high energy and power in any of the current electrochemical devices," said Nobuyuki Zettsu, as first author on the paper.

Lithium ion batteries are rechargeable and power such devices as cell phones, laptops, power tools, and even store power for the electrical grid. They're particularly sensitive to temperature fluxes, and have been known to cause fires or even explosions. In response to the problems with liquid electrolytes, scientists are working toward developing a better all-solid-state battery without liquid.

"Despite the expected advantages of all-solid-state batteries, their power characteristic and energy densities must be improved to allow their application in such technologies as long-range electric vehicles," Zettsu said. "The low rate capabilities and low energy densities of the all-solid-state batteries are partly due to a lack of suitable solid-solid heterogeneous interface formation technologies that exhibit high iconic conductivity comparable to liquid electrolyte systems."

Zettsu and his team grew garnet-type oxide solid electrolyte crystals in molten LiOH used as a solvent (flux) on a substrate that bonded the electrode into a solid state as they grew. A specific crystal compound known to grow cubically allowed the researchers to control the thickness and connection area within the layer, which acts as a ceramic separator.

"Electron microscopy observations revealed that the surface is densely covered with well-defined polyhedral crystals. Each crystal is connected to neighboring ones," wrote Zettsu.

Zettsu also said that the newly grown crystal layer could be the ideal ceramic separator when stacking the electrolyte layer on the electrode layer.

"We believe that our approach having robustness against side reactions at the interface could possibly lead to the production of ideal ceramic separators with a thin and dense interface," wrote Zettsu, noting that the ceramics used in this particular experiment were too thick to be used in solid batteries. "However, as long as the electrode layer can be made as thin as 100 microns, the stacking layer will operate as a solid battery."

One hundred microns is about the width of a human hair, and slightly less than twice the thickness of a standard electrode layer in contemporary lithium-ion batteries. "All-solid-state batteries are promising candidates for energy storage devices," Zettsu said, noting that several collaborations between researchers and private companies are already underway with the ultimate goal of displaying all-solid-state battery samples at the 2020 Olympic games in Tokyo.

Zettsu and other researchers plan to fabricate prototype cells for electric vehicle use and for wearable devices by 2022.


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More information: Nobuyuki Zettsu et al, Thin and Dense Solid-solid Heterojunction Formation Promoted by Crystal Growth in Flux on a Substrate, Scientific Reports (2018). DOI: 10.1038/s41598-017-18250-9
Journal information: Scientific Reports

Provided by Shinshu University
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Feb 27, 2018
When our batteries go in one or both of our EVs, I expect to replace then with 600-mile units.

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