'Workhorse' lithium battery could be more powerful thanks to new design

'Workhorse' lithium battery could be more powerful thanks to new design
Snehashis Choudhury, Ph.D. '18, left, and Lynden Archer in Archer's Kimball Hall office. Credit: Tom Fleischman

Cornell University chemical engineering professor Lynden Archer believes there needs to be a battery technology "revolution—and thinks that his lab has fired one of the first shots.

"What we have now [in lithium-ion battery technology] is actually at the limits of its capabilities," said Archer. "The lithium-ion battery, which has become the workhorse in powering new electronics technologies, operates at over 90 percent of its theoretical storage capacity. Minor engineering tweaks may lead to better batteries with more storage, but this is not a long-term solution."

"You need a kind of radical mindset change," he said, "and that means that you've got to almost start at the beginning."

Snehashis "Sne" Choudhury, Ph.D. '18, has come up with what Archer terms an "elegant" solution to a fundamental problem with rechargeable batteries that use energy-dense metallic lithium anodes: sometimes-catastrophic instability due to dendrites, which are spines of lithium that grow from the anode as ions travel back and forth through the electrolyte during charge and discharge cycles.

If the dendrite breaks through the separator and reaches the cathode, short-circuiting and fire can occur. Solid electrolytes have been shown to suppress dendrite growth mechanically, but at the expense of fast ion transport. Choudhury's solution: Confine dendrite growth by the structure of the electrolyte itself, which can be controlled chemically.

Using a reaction procedure the Archer group introduced in 2015, they employ "cross-linked hairy nanoparticles—a graft of silica nanoparticles and a functionalized polymer (polypropylene oxide) - to create a porous electrolyte that effectively lengthens the route ions must take to travel from the anode to the cathode and back, dramatically increasing the life of the anode.

Their paper, "Confining Electrodeposition of Metals in Structured Electrolytes," was published in Proceedings of the National Academy of Sciences. Choudhury and Dylan Vu—a rising junior majoring in chemical engineering—are co-first authors.

Choudhury, who is headed to Stanford University for his postdoctoral work, also devised a method for direct visualization of the inner workings of their experimental battery. The group confirmed theoretical predictions about growth with Choudhury's device.

"This is something I've wanted to do for, I guess, three Ph.D. students' lifetimes," said Archer, who's been at Cornell since 2000, with a laugh. "What Sne was able to do was design a cell that allowed us to, very elegantly, visualize what is occurring at the lithium-metal interface, giving us now the ability to go beyond theoretical predictions."

Another novelty of this work, Archer said, is "overturning something of a canon" in battery science. It's long been held that, in order to suppress , the separator inside the must be stronger than the metal it is trying to suppress, but Choudhury's porous polymer separator—with average pore sizes below 500 nanometers—were shown to arrest the growth.


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More information: Snehashis Choudhury et al, Confining electrodeposition of metals in structured electrolytes, Proceedings of the National Academy of Sciences (2018). DOI: 10.1073/pnas.1803385115
Provided by Cornell University
Citation: 'Workhorse' lithium battery could be more powerful thanks to new design (2018, June 25) retrieved 20 November 2018 from https://techxplore.com/news/2018-06-workhorse-lithium-battery-powerful.html
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