Discovery sheds light on synthesis, processing of high-performance solar cells

solar panels
Credit: CC0 Public Domain

Halide perovskite solar cells hold promise as the next generation of solar cell technologies, but while researchers have developed techniques for improving their material characteristics, nobody understood why these techniques worked. New research sheds light on the science behind these engineering solutions and paves the way for developing more efficient halide perovskite solar cells.

"This is about material design," says Aram Amassian, co-corresponding author of a paper on the work and an associate professor of science and engineering at North Carolina State University.

"If you want to intentionally engineer halide that have the desirable characteristics you're looking for, you have to understand not only how the material behaves under different conditions, but why," Amassian says. "This work gives us a fuller understanding of this class of materials, and that understanding will illuminate our work moving forward."

Halide perovskites are basically salts, with positively and negatively charged components that come together to form a neutral compound. And they have several characteristics that make them desirable for manufacturing high-efficiency solar . They can be dissolved into a liquid and then form high-quality crystals at low temperatures, which is attractive from a manufacturing standpoint. In addition, they are easy to repair and can tolerate defects in the material without seeing a big drop-off in their semiconductor properties.

An international team of researchers delved into a key phenomenon related to halide perovskite solar cell synthesis and processing. It involves the fact that adding cesium and rubidium into the synthesis process of mixed halide perovskite compounds makes the resulting solar cell more chemically homogeneous—which is desirable, since this makes the material's characteristics more uniform throughout the cell. But until now, no one knew why.

To investigate the issue, the researchers used time-resolved, X-ray diagnostics to capture and track changes in the crystalline compounds formed throughout the synthesis process. The measurements were performed at the Cornell High Energy Synchrotron Source.

"These studies are critical in defining the next steps toward the market readiness of perovskite-based solar cells," says Stefaan De Wolf, co-corresponding author of the paper and an associate professor of materials science and engineering at the King Abdullah University of Science and Technology (KAUST).

"What we found is that some of the precursors, or ingredients, want to form several compounds other than the one we want, which can cluster key elements irregularly throughout the material," Amassian says. "That was something we didn't know before.

"We also found that introducing cesium and rubidium into the process at the same time effectively suppresses the formation of those other compounds, facilitating the formation of the desired, homogeneous perovskite compound that is used to make high performance solar cells."

Next steps for the work include translating these lessons from laboratory-based spin-coating to large area manufacturing platforms which will enable the high throughput fabrication of perovskite solar cells.


Explore further

Adding guanidinium thiocyanate to mixed tin-lead perovskites to improve solar cell efficiency

More information: Hoang X. Dang et al, Multi-cation Synergy Suppresses Phase Segregation in Mixed-Halide Perovskites, Joule (2019). DOI: 10.1016/j.joule.2019.05.016
Journal information: Joule

Citation: Discovery sheds light on synthesis, processing of high-performance solar cells (2019, June 6) retrieved 17 June 2019 from https://techxplore.com/news/2019-06-discovery-synthesis-high-performance-solar-cells.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.
213 shares

Feedback to editors

User comments

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more